The case for ancient life on Mars just got harder to dismiss. A new NASA-led study argues that the long-chain organic molecules discovered in Martian mudstone are difficult to explain through non-biological processes alone. The research, led by Alexander Pavlov of NASA's Goddard Space Flight Center, re-examined the Mars organics found by the Curiosity rover and concluded that their original abundance points to a source that chemistry without life struggles to account for, according to ScienceAlert's report on the findings.

The Mars organics in question are alkanes — chain-shaped hydrocarbons with 10, 11, and 12 carbon atoms, known as decane, undecane, and dodecane. They are the longest organic molecules ever found on Mars, detected by Curiosity's Sample Analysis at Mars instrument in a rock dubbed Cumberland, drilled in 2013 at Yellowknife Bay inside Gale Crater. The findings were published in the Proceedings of the National Academy of Sciences, led by astrochemist Caroline Freissinet of France's National Centre for Scientific Research, as Sky at Night Magazine reported. The rocks holding them are around 3.7 billion years old, dating to the era when life first emerged on Earth.

What the new study actually calculated

Pavlov's team started from a puzzle: the measured concentration of alkanes in the sample was modest, roughly 30 to 50 parts per billion. But the Cumberland mudstone has sat near the Martian surface, bombarded by cosmic radiation, for about 80 million years — and radiation steadily shreds organic material. Drawing on laboratory radiolysis experiments, the researchers estimated how much of the Mars organics must have been present before that long exposure. Their answer: an original concentration between 120 and 7,700 parts per million, vastly more than what survives today.

That inferred abundance is the crux. The team then tallied every known non-biological route that could have stocked the rock with organics: delivery by interplanetary dust and meteorites, fallout from atmospheric haze, hydrothermal chemistry, and water-rock reactions such as serpentinization. Even combined, those processes could not approach the estimated original quantities. Something else, the study argues, must have contributed — and on Earth, molecules like these are produced largely, though not exclusively, by living things.

Why alkanes matter in the search for life

Like all Mars organics, these molecules are built from carbon and hydrogen, and such chemistry is considered a prerequisite for life as we know it — but they can also form without it. The intrigue here is structural. The Mars organics appear to be fragments of even longer chains, possibly long-chain fatty acids. In terrestrial biology, fatty acids are ubiquitous components of cell membranes. Abiotic chemistry can make them too, particularly around hydrothermal vents, which is why scientists are careful to call this evidence consistent with life rather than evidence of it.

The preservation of these Mars organics is part of the story. Long-chain alkanes are fragile, far more delicate than the ring-shaped carbon molecules previously found on Mars. That they survived billions of years in clay-rich rock tells researchers that Mars can preserve delicate chemistry over geological time — meaning that if biosignatures exist in similar sediments, future missions have a realistic shot at finding them. The study cannot distinguish whether the molecules came from biology or from unknown abiotic chemistry, a limitation the authors acknowledge: the conclusion rests on modeling how radiation destroys organics, not on a direct detection of life.

What comes next

Definitive answers will likely require getting Martian rock back to Earth laboratories, where instruments far more sensitive than anything on a rover can dissect the chemistry atom by atom. That is the long-term job of the Perseverance rover's cached sample tubes waiting in Jezero crater. In the meantime, the Pavlov study sharpens the question rather than settling it: the chemistry of early Mars looks increasingly like the chemistry that, on Earth, accompanied the origin of life. Whether these Mars organics turn out to be a hint of ancient biology or a lesson in exotic geochemistry, they have earned their place among the most tantalizing clues Curiosity has ever uncovered.

For more space and science coverage, see the Science topic page, including how Mars probes captured an interstellar comet's closest view. The red planet keeps offering hints — and each one makes the next mission a little more urgent.